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PUBLICATIONS

Combustion and Gasification

Adams, T.N., Frederick, W.J., Grace, T.M., Hupa, M., Iisa, K., Jones, A.K., Tran, H.N., Kraft Recovery Boilers, TAPPI Press, Atlanta, 1997.

Frederick, W.J. Jr.; Vakkilainen, E.K. Sintering and Structure Development in Alkali Metal Salt Deposits Formed in Kraft Recovery Boilers, Energy & Fuels, 17(6), 1501 – 1509 (2003).

Nohlgren, I., Sricharoenchaikul, V., Sinquefield, S., Frederick, W.J and Theliander, H., “Black Liquor Gasification with Direct Causticization using Titanates in a Pressurized Entrained-Flow Reactor, Part 1: Kinetics of the Causticization Reaction”, Journal of Pulp and Paper Science , Vol. 29, No. 4, p. 107-113 (2003).

Gea, G.; Murillo, M. B.; Arauzo, J.; Frederick, W.J. Jr. Swelling Behavior of Black Liquor from Soda Pulping of Wheat Straw. Energy & Fuels (2003) 17(1), 46 – 53.

Sricharoenchaikul, V.; Frederick, W.J.; Agrawal, P. Carbon distribution in char residue from gasification of kraft black liquor. Biomass and Bioenergy (2003), 25(2), 209-220.

Sricharoenchaikul, V; Agrawal, P.; Frederick, W.J. Jr. Black Liquor Gasification Characteristics. 1. Formation and Conversion of Carbon-Containing Product Gases during Gasification of Black Liquor. Industrial & Engineering Chemistry Research (2002), 41(23), 5640 - 5649.

Sricharoenchaikul, V; Agrawal, P.; Frederick, W.J. Jr. Black Liquor Gasification Characteristics. 2. Measurement of Condensable Organic Matter (Tar) At Rapid Heating Conditions. Industrial & Engineering Chemistry Research (2002), 41(23): 5650 – 5658.

Sutinen, J.; Karvinen, R.; Frederick, W. J., Jr.. A Chemical Reaction Engineering and Transport Model of Kraft Char Bed Burning. Industrial & Engineering Chemistry Research (2002), 41(6), 1477-1483.

Sricharoenchaikul, V.; Hicks, A.L.; Frederick, W J. Jr. Carbon and char residue yields from rapid pyrolysis of kraft black liquor. Bioresour. Technol. (2001), 77(2), 131-138.

Lindblom, Josefina; Frederick, W. James; Lien, Steven J.; Theliander, Hans. Sintering of recovery boiler dust: the influence of the composition of the dust. AIChE Symp. Ser. (2000), 324, 20-27.

Larson, E.; McDonald, G.; Yang, W.; Frederick, W.; Iisa, K.; Kreutz, T.; Malcolm, E.; Brown, C. “Cost-Benefit Assessment of Black-Liquor Gasifier/Combined-Cycle Technology Integrated into a Kraft Pulp Mill,” Tappi J. 83(6):57 (2000).

Frederick, W.J. Jr., V. Phimolmas, K. Iisa, “The Effect of Temperature and Residence Time on the Distribution of Carbon, Sulfur and Nitrogen between Gaseous and Condensed Phase Products from Low Temperature Pyrolysis of Kraft Black Liquor,” AIChE Symp. Ser., 95(322):119-127 (1999).

Techakijkajorn, U., Frederick, W.J., Tran, H.N., “Sintering and Densification of Recovery Boiler Deposits: Laboratory Data and a Rate Model,” J. Pulp Paper Sci., 25(3):73-80 (1999).

Sricharoenchaikul, V. Phimolmas, V., Frederick, W. J. Jr., Grace, T.M., “Pyrolysis of Kraft Black Liquor: Formation and Thermal Conversion of Volatile Products and Char.” J. Pulp Paper Sci. 24(2):J43-50 (1998).

Wåg, K.J., Frederick, W.J., Dayton, D.C., Kelley, S.S., “Characterization of Black Liquor Char Gasification using Thermogravimetry and Molecular Beam Mass Spectrometry,” in Further Advances in the Forest Products Industries, P. W. Hart, ed., AIChE Symp. Ser., 93(315):67-76 (1997).

Boonsongsup, L., K. Iisa, and W.J. Frederick, “Kinetics of Sulfation of NaCl at Combustion Conditions.” Industrial and Engineering Chemistry, 36(10):4212-4216 (1997).

Sricharoenchaikul, V.; Frederick, W.J.; Grace, T.M., Sulfur Species Transformations During Pyrolysis of Kraft Black Liquor.” J. Pulp Paper Sci. 23, 8: J394-400 (1997).

Wåg, K.J., Reis, V.V., Frederick, W.J., Grace, T.M., Mathematical model for the release of inorganic emissions during black liquor char combustion.” TAPPI J., 80(5):135-145 (1997).

Dayton, D.C., Frederick, W.J., 1996, "Direct Observation of Alkali Vapor Release During Biomass Combustion and Gasification. 2. Black Liquor Combustion at 1100°C." Energy&Fuels, 10(2):284-292 (1996).

Frederick, W.J., Iisa, K., Lundy, J.R., O’Connor, W.K., Reis, K., Scott, A.D., Sinquefield, S.A., Scricharoenchaikul, V., and Van Vooren, C.A., “Energy and materials from recycled paper sludge,” Tappi Jl., 79(6):123-131 (1996).

Stenberg, J., Frederick, W. J., Boström, S., Hernberg, R., Hupa, M., 1996, "Pyrometric temperature measurement method and apparatus for measuring particle temperatures in hot furnaces,” Review of Scientific Instruments, 67(5):1976-1984 (1996).

Reis, V. V., Frederick, W. J. ,Wåg, K. J. , Iisa, K., and Sinquefield, S. A., "The Effects of Temperature and Oxygen Concentration on Potassium and Chloride Enrichment During Black Liquor Combustion," Tappi Jl., 78(12):67-76 (1995).

Whitty, K.J., M. Hupa, and W.J. Frederick, “Gasification of Black Liquor Char with Steam at Elevated Pressures,” J. Pulp Paper Sci., 21(6):J214-J221 (1995).

Mikkanen, P., E.I. Kauppinen, J.K. Jokiniemi, S.A. Sinquefield, and W.J. Frederick, “Bimodal Fume Particle Size Distributions from Recovery Boiler and Laboratory Scale Black Liquor Combustion,” Tappi Jl., 77(12):81-84 (1994).

Mikkanen, P., E.I. Kauppinen, J.K. Jokiniemi, S.A. Sinquefield, W.J. Frederick, and M. Mäkinen, “The Particle Size and Chemical Species Distributions of Aerosols Generated in Kraft Black Liquor Pyrolysis and Combustion,” AIChE Symp. Ser., vol. 90, no. 302, pp. 46-54 (1994).

Boonsongsup, L., K. Iisa, and W.J. Frederick, “SO2 Capture and HCl Release at Kraft Recovery Boiler Conditions,” AIChE Symp. Ser., vol. 90, no. 302, pp. 39-45 (1994).

Frederick, W.J., M. Hupa, J. Stenberg, and R. Hernberg, “Optical Pyrometric Measurements of Surface Temperatures During Black Liquor Char Burning and Gasification,” Fuel, 73(12):1889-1894 (1994).

Frederick, W.J., K. Wåg, and M. Hupa, “Rate and Mechanism of Black Liquor Char Gasification with CO2 at Elevated Pressures,” Ind. Eng. Chem. Research, 32(8):1747-1753 (1993).


Evaporation and Evaporator Fouling

Shi, B.; Frederick, W.J. Jr.; Rousseau, R.W. Nucleation, Growth, and Composition of Crystals Obtained from Solutions of Na2CO3 and Na2SO4. Industrial and Engineering Chemistry Research, 42(25), 6343 – 6347 (2003).

Shi, B.; Frederick Jr., W.J.; Rousseau, R.W. Effects of calcium and other ionic impurities on the primary nucleation of burkeite. Industrial and Engineering Chemistry Research, v 42, n 12, Jun 11, 2003, p 2861-2869.

Euhus, D.D.; Rousseau, R.W.; Frederick, W.J. Jr.; Schmidl, W.; Lien S.J.; Thorn, P.A.; Smith, P.K. Eliminating Sodium Salt Fouling in Black Liquor Concentrators: Crystallization Behavior and Fouling in Pilot Evaporation Trials. Proc. TAPPI Fall Technical Conference, Tappi Press, Atlanta (October, 2003).

Euhus, D. D.; Shi, B.; Rousseau, R.W.; Frederick, W.J. Jr. Control of Soluble Scale in Black Liquor Evaporators and Concentrators: Part 1. Pilot Plant Studies, Paper 72-1, Proc .TAPPI Fall Technical Conference, TAPPI Press, Atlanta, 2002.

Frederick, W.J. Jr.; Shi, B.; Euhus, D.D.; Rousseau, R.W.; Control of Soluble Scale in Black Liquor Evaporators and Concentrators: Part 2. Interpretation of Crystallization Results. Paper 72-2, Proc. TAPPI Fall Technical Conference, Tappi Press, Atlanta (October, 2002).

Shi, B.; Frederick, W.J.Jr.; Rousseau, R.W. Tracking and Controlling Nucleation in Complex Fluids. Proc. 15th International Symposium on Industrial Crystallization, September 15 - 18, 2002, Sorrento, Italy.

Euhus, D.D., Rousseau, R.W., Frederick, W.J.Jr.; Lien, S.J. “Black Liquor Evaporation: Links between Nucleation in the Bulk and Fouling of Heat Transfer Surfaces,” Separations Technology Topical Conference, AIChE, New York, 2001, pp. 236-241.

Shi, B., Rousseau, R.W., Frederick, W.J. Jr. Nucleation of Burkeite from Aqueous Solutions and Black Liquor. Proc. 2001 TAPPI-CPPA Intl. Chem Recovery Conf., PAPTAC, Montreal, p. 177-181.

Euhus, D.D., Rousseau, R.W., Frederick, W.J. Jr., Lien, S.J. Sodium Salt Fouling in Falling-Film Evaporators: A Pilot Study, Proc. 2001 TAPPI-CPPA Intl. Chem Recovery Conf., PAPTAC, Montreal, p. 183-193.


Non-Process Elements and Equilibrium in Aqueous, Ionic Systems

Frederick, W. J. Jr., G. L. Rorrer, A. W. Rudie, G. W. Schmidl, S. A. Sinquefield, M. L. Laver, W. Yantasee, D. Ming, “Control of the Accumulation of Non-Process Elements in Pulp Mills with Bleach Filtrate Reuse: A Chemical Equilibrium Approach to Predicting the Partitioning of Metals In Pulp Mill and Bleach Plant Streams.” Final Report, U.S. DOE Project Number: DE-FC07-96ID13441, October 2000.

Frederick, W.J. Jr., M. McAleer, W. Schmidl, A.W. Rudie, A.J. Gerbino, G.L. Rorrer, W. Yantasee, "Modeling the Fate of Metal Ions During Brownstock Washing with Bleaching Filtrate Recycle," AIChE Symp. Ser., 95(322):21-30 (1999).

Frederick, W.J., W-Y. Yoon, Zurong Yang, and G.P. Golike, “The Rate of Calcium Sulfate Fouling in Sulfite Spent Liquor Evaporators,” AIChE 1992 Forest Products Symposium Proceedings, TAPPI Press, Atlanta, pp. 65-74 (1993).

Luh, S.P. and W.J. Frederick, “Phase Behavior of Sodium Lignosulfonates in Water-Ethanol Mixtures,” Holzforschung, 46:325-330 (1992).

Gasteiger, H.A., W.J. Frederick, and R.C. Streisel, “Solubility of Aluminosilicates in Alkaline Solutions and a Thermodynamic Equilibrium Model,” Ind. Eng. Chem. Research, 31(4):1183-1189 (1992).

Frederick, W.J., R. Krishnan, and R.J. Ayers, “Pirssonite Deposits in Green Liquor Processing,” TAPPI Journal, 73(2):135-140 (1990).

Frederick, W.J., B. Kelly, H.C. Kim, M.J. McIntyre, and J.P. Danko, “Modeling Electrolyte Behavior in Pulp and Paper Processes,” in Chemical Engineering Technology in Forest Products Processing, B. Crowell, editor, AIChE Forest Products Division, Tacoma, WA (1988), pp. 87-96.

Kim, H.T. and W.J. Frederick, “Evaluation of Pitzer Ion Interaction Parameters of Aqueous Electrolytes at 25°C. 1. Single Salt Parameters,” J. Chem. and Eng. Data, v. 33, no. 2, (1988), p. 177.

Kim, H.T. and W.J. Frederick, “Evaluation of Pitzer Ion Interaction Parameters of Aqueous Electrolytes at 25°C. 2. Ternary Mixing Parameters,” J. Chem. and Eng. Data, v. 33, no. 3, (1988).


 
     
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